Distinguish between the following terms: l)r9)qya:gc/(xyg 9 aeirke ;

1.Precision and accuracy.
2.Systematic error and random error.

  Which of the following i5ibi4*h2jfmdox6p h 4 s correct?

  A thermometer was used to record the temperaturep8n6ulqpy a)go,; ve) of pure boiling water at sea level t ey vuq )anpp)g8l,;6ohree times and the values were : $85.6^{\circ}C$,$85.7^{\circ}C$,$85.5^{\circ}C$.What can be said about the accuracy and precision of these values?

  Which statement best describes the relationship between x and y on the graph bel3)vh/eb 5ci- f3rom5agl. z kk 3chv / mekb)g53ar ol-z5fk.iow?

  For a first order reaction, the relationship between rate and0 gxnn +b5pu4g08ykit md;/rd the concentration of a reactant, [A], can be shown using the following equation: rated n+8np0k;iyt4 gdxmr 0g/ub5 =k[A].
The data below gives the rate information for the first order reaction that proceeds in the thermal decomposition of reactant A.



1.On the axes above, draw a graph based on the provided data.
2.The effect of time on the concentration of reactant B for a zero-order reaction was plotted on the graph below.


(i)Draw a line of best fit on the graph above.
2.2.Describe the relationship between time and concentration.
Concentration  ----待选择----decreasesincreases  linearly with time

  The relationship between pressure and temperature of a known volume 9bg xjojv.x7v4 dmz**and amount of gas can be described using Gay-Lussac’s law which states that pressure is directly proportional to temperatur. v47oj v9dz*g*bmx xje.
P∝T
Where P is pressure in Pa, and T is temperature in K.


1.On the axes above, sketch the graph of P∝T.

2.State two features that would need to be added to your sketched graph to turn it into a drawn graph.

3.The proportionality can be shown in an equation by incorporating a constant, k. The equation becomes P=kT, and follows the format of the equation of a straight line.

3.1.State the feature of a straight line that k represents in this context.
3.2.Deduce the y-intercept of the straight line.straight line=  (Pa)

  Solid sodium carbonate 1umf/dzb (c mz npd18t0e/z 0jreacts with excess nitric acid of 0.10 mol dm$^{-3}$ as shown in the equation below:
$Na_2CO_3$(s) + 2$HNO_3$(aq)→$H_2O$(l) + $CO_2$(g) + 2$NaNO_3$(aq)
1.State a method to measure the rate of reaction other than measuring the volume of gas collected.
2.1.Sketch a graph to show the volume of gas produced over time.
2.2.Explain the shape of your graph using the collision theory.
$CO_2$ is produced in the reaction; hence, the volume of $CO_2$  ----待选择----increasesdecreases  over time.
3.On the same graph as in part(bi), sketch another line to show the volume of gas collected over time at a concentration of 0.05 mol dm$^{-3}$ of nitric acid and label it as X.
4.Suggest and describe a factor other than the concentration that can affect the rate of the above reaction.

  The enthalpy of neutralization for the reaction between sulfuric acid and p ye;s 0dh lu6m-k7q)llotassium )0h 7qdk;e6lymll -su hydroxide can be determined experimentally.
$H_2SO_4$(aq)+2KOH(aq)→$K_2SO_4$(aq)+2$H_2O$(l)
A student recorded the temperature of 20.0 cm$^3$ of 0.500 mold m$^{-3}$ sulfuric acid every minute. At four minutes,25.0cm$^3$ KOH(aq) is added to the solution, stirred immediately, and temperature recorded for another four minutes. The results are represented in the graph below.



1.Calculate the lowest concentration of aqueous KOH that must be used to ensure it is in excess.
n$_{KOH}$=  mol;C$_{KOH}$=  mold m$^{-3}$
2.Use the graph above to estimate a value for the maximum temperature change, ΔT.
ΔT=  °C
3.State one assumption you made in part (b).
4.Identify the anomalous result and suggest a possible type and source of error.
5.In another experiment with the same reactants, the student measured the initial and final temperatures and presented their results below:
Initial Temperature (°C ± 0.1°C) 24.8 25.1 24.9
Final Temperature (°C ± 0.1°C) 26.4 26.6 26.4
5.1.Calculate the average change in temperature (ΔT) giving its percentage uncertainty.
Average=  °C
5.2.Use sections 1 and 2 of the data booklet to calculate the energy released and its uncertainty. You may assume that the only source of uncertainty is from the temperature change.
Energy released (q)=  J

1.State the complete balanced equation for the reaction between sulphuric aciv-jjm tb(2qslhe+iz(/ b)6 ond and c+snq)zl 6b/vbeotm((hj ij -2 opper (II) oxide.
2.State the complete balanced equation for the reaction between ethanoic acid and potassium carbonate.
3.Outline two ways to monitor the rate of reaction for reaction (b) above.

  The relationship between energy, E, and wavelength, λ, is shown according kdkxyn4( t,f;to the,4k; k(fnd ytx equation below.
E=$\frac{hc}{λ}$


Which of the below statements are correct for the graph below representing E=$\frac{hc}{λ}$
?
I. Energy and wavelength are directly proportional
II.The units for the gradient are J m$^{-1}$
III.The y-intercept has the units J

  The feasibility of a reaction proceeding spontaneously can be predictr*oag(-m 0ybp ed using the fol- b(romayp* g0lowing equation:
ΔG=−TΔS+ΔH.
Where ΔG is the change in Gibb’s free energy, ΔS is the change in entropy, and ΔH is the change in enthalpy.


1.When ΔG<0, a reaction can be described as spontaneous. Use the graph above to deduce the lowest temperature at which the reaction becomes spontaneous.
Read graph at ΔG=0,  K.
2.Calculate the gradient of the line and state its units.
3.Use your answer to part (b) to deduce the value and correct units for ΔS.
4.Use the graph to determine the value for ΔG when the temperature is raised to 675K.
Extrapolation of the line=  (kJ mol$^{-1}$)
5.Calculate a value for y-intercept=  and state the correct units {kJmol$^{-1}$|kJmol$^{-1}K^{-1}$}.

  The potential of a cell under non-standard conditiqa)7c(4ltzw hc xi4 1*d (qabuons can be calculated using the Nernst equation:1l4abc (4q awduxc th i7q)(*z
E=E$^θ$-$\frac{RT}{nF}$lnQ
For the graph below, which components of the equation represent the gradient and the y-intercept?

  The relationship between the concentn30 hyq;8d1l3 rxd bmpration of a reactant, A, and the time, for a second-qh0dx8 p;3dy 1mln3rborder reaction can be expressed using the equation below:
$\frac{1}{[A]}$=kt+$\frac{1}{[A]_0}$
Where [A] is the concentration of reactant A,[A] is the initial concentration of reactant $[A]_0$,t is the time in seconds,and k is a constant.


1.Calculate the gradient of the line and state the correct units.The number=  
2.Use the graph to determine $[A]_0$(also known as the initial concentration of A).
$[A]_0$=  mol dm$^{-3}$
3.Determine the time at which the concentration of A is equal to an eighth of its initial concentration.
[A]=  mol m$^{-3}$
(If you were unable to complete parts (a), and (b), you may use k=0.02, and $[A]_0$ =42).

  25.00 cm$^3$ of 0.100 mold m$^{-3}$$HNO_3$ was titrated against 0.200 mold m$^{-3}$$NaOH$.The volumes of NaOH delivered for the three trials 14.00 cm$^3$ ,14.05 cm$^3$ and 14.00 cm$^3$.
Which statement below best describes these results?